ChansonRolandV6, France, Analysis, bibRecord, 000076

Chiral N-Heterocyclic Carbenes as Stereodirecting Ligands in Asymmetric Catalysis

Identifieur interne : 000076 ( France/Analysis ); précédent : 000075; suivant : 000077

Chiral N-Heterocyclic Carbenes as Stereodirecting Ligands in Asymmetric Catalysis

Auteurs : Lutz H. Gade [Allemagne] ; Stéphane Bellemin-Laponnaz [France]

Source :

Topics in Organometallic Chemistry [ 1436-6002 ]

RBID : ISTEX:097F27625E8A031EF7F369A8B29FECF7443E160D

English descriptors

Teeft :
- Active catalyst, Aldehyde, Alkylation, Angew, Angew chem, Aryl, Arylboronic acid, Asymmetric, Asymmetric catalysis, Asymmetric hydrogenation, Asymmetric hydrosilylation, Asymmetry, Bidentate, Bidentate ligand, Binaphthyl, Bolm, Carbene, Carbene ligand, Carbenes, Catalysis, Catalyst, Catalytic, Chem, Chem commun, Chiral, Chiral base, Chiral carbenes, Chiral element, Chiral induction, Chiral information, Chiral ligand, Chiral nhcs, Chirality, Commun, Complexation, Coordination chemistry, Crabtree, Derivative, Enantiomeric, Enantiomeric excess, Enantioselective, Enantioselectivities, Enantioselectivity, Enders, Enones, Gade, Helmchen, Heterocycle, Hoveyda, Hydrogenation, Hydrosilylation, Imidazolinium, Imidazolinium salt, Imidazolinylidenes, Imidazolium, Imidazolium salt, Ketone, Kinetic resolution, Lett, Ligand, Ligand design, Ligand precursor, Ligand system, Metal center, Metathesis, Nhcs, Organometallics, Oxazoline, Oxazoline ring, Palladium, Phosphine, Planar chirality, Precursor, Reaction product, Reagent, Rhodium, Rhodium complex, Rovis, Secondary alcohol, Selectivity, Stereodirecting, Stereodirecting ligand, Stereoselective, Steric, Substituents, Tetrahedron, Togni, Triazolium.

Abstract

Abstract: After the first attempts to use chiral NHC ligands in asymmetric catalysis in the late 1990s, which initially met with only limited success, several novel structural concepts have emerged since the beginning of this decade that have led, literally, to an explosion in the field. With a significant number of highly selective chiral catalysts based on chiral NHCs having been reported very recently, several general trends in the design of new NHC-containing molecular catalysts for stereo-selective transformations in organic synthesis have emerged. This development is the focus of this review.

Url:

https://api.istex.fr/ark:/67375/HCB-DTXH92Q2-2/fulltext.pdf

DOI: 10.1007/978-3-540-36930-1_5

Affiliations:

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to stream Main, to step Exploration: 000F54
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Links to Exploration step

ISTEX:097F27625E8A031EF7F369A8B29FECF7443E160D

Le document en format XML

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Chiral N-Heterocyclic Carbenes as Stereodirecting Ligands in Asymmetric Catalysis

Chiral N-Heterocyclic Carbenes as Stereodirecting Ligands in Asymmetric Catalysis

Source :

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

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